JPS59156911A - 火山ガラスを主原料とするａ型ゼオライトの製造方法 - Google Patents
火山ガラスを主原料とするａ型ゼオライトの製造方法Info
- Publication number
- JPS59156911A JPS59156911A JP2917183A JP2917183A JPS59156911A JP S59156911 A JPS59156911 A JP S59156911A JP 2917183 A JP2917183 A JP 2917183A JP 2917183 A JP2917183 A JP 2917183A JP S59156911 A JPS59156911 A JP S59156911A
- Authority
- JP
- Japan
- Prior art keywords
- volcanic glass
- sodium
- zeolite
- sodium metasilicate
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010457 zeolite Substances 0.000 title claims abstract description 28
- 239000005335 volcanic glass Substances 0.000 title claims abstract description 26
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000007858 starting material Substances 0.000 title description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 48
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 18
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910001868 water Inorganic materials 0.000 claims abstract description 15
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 7
- 239000013078 crystal Substances 0.000 claims description 19
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 13
- 238000002425 crystallisation Methods 0.000 claims description 5
- 230000008025 crystallization Effects 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052979 sodium sulfide Inorganic materials 0.000 claims 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 48
- 229910052742 iron Inorganic materials 0.000 abstract description 24
- 238000000034 method Methods 0.000 abstract description 14
- 239000003599 detergent Substances 0.000 abstract description 10
- 238000002386 leaching Methods 0.000 abstract 1
- 239000004576 sand Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 11
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- 238000010828 elution Methods 0.000 description 7
- 238000005342 ion exchange Methods 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000005070 ripening Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000975357 Salangichthys microdon Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- WHOPEPSOPUIRQQ-UHFFFAOYSA-N oxoaluminum Chemical compound O1[Al]O[Al]1 WHOPEPSOPUIRQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2917183A JPS59156911A (ja) | 1983-02-22 | 1983-02-22 | 火山ガラスを主原料とするａ型ゼオライトの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2917183A JPS59156911A (ja) | 1983-02-22 | 1983-02-22 | 火山ガラスを主原料とするａ型ゼオライトの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59156911A true JPS59156911A (ja) | 1984-09-06 |
| JPH0559045B2 JPH0559045B2 (en]) | 1993-08-30 |
Family
ID=12268790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2917183A Granted JPS59156911A (ja) | 1983-02-22 | 1983-02-22 | 火山ガラスを主原料とするａ型ゼオライトの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59156911A (en]) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991017954A1 (de) * | 1990-05-17 | 1991-11-28 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung von zeolithen aus getempertem sand |
| EP0963949A1 (en) * | 1998-06-12 | 1999-12-15 | Teruo Henmi | Method of producing artificial zeolite |
| JP2012041251A (ja) * | 2010-08-23 | 2012-03-01 | Nippon Kensetsu Gijutsu Kk | ゼオライトの製造方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5263200A (en) * | 1975-11-20 | 1977-05-25 | Sanki Eng Co Ltd | Process for preparing zeolite employing sillus as raw material |
-
1983
- 1983-02-22 JP JP2917183A patent/JPS59156911A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5263200A (en) * | 1975-11-20 | 1977-05-25 | Sanki Eng Co Ltd | Process for preparing zeolite employing sillus as raw material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991017954A1 (de) * | 1990-05-17 | 1991-11-28 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung von zeolithen aus getempertem sand |
| EP0963949A1 (en) * | 1998-06-12 | 1999-12-15 | Teruo Henmi | Method of producing artificial zeolite |
| JP2012041251A (ja) * | 2010-08-23 | 2012-03-01 | Nippon Kensetsu Gijutsu Kk | ゼオライトの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0559045B2 (en]) | 1993-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5417951A (en) | Process for the hydrothermal production of crystalline sodium disilicate | |
| US3310373A (en) | Method for producing crystalline aluminosilicates | |
| JP7190577B2 (ja) | ゼオライトおよびその製造方法 | |
| EP0609270B1 (en) | Process for preparing uniform mfi-type zeolite crystals | |
| JPH05503065A (ja) | 結晶二珪酸ナトリウムの熱水製造方法 | |
| CA1213872A (en) | Process for preparation of zeolites | |
| US4530824A (en) | Process for preparation of L type zeolites | |
| PL117556B1 (en) | Continuous process for zeolite a manufactre | |
| US4089929A (en) | Process for the production of low-iron zeolitic aluminosilicates | |
| US3343913A (en) | Table iv | |
| CA1132962A (en) | Preparing zeolite naa | |
| CN108706614B (zh) | 一种活性硅铝粉及其制备方法 | |
| DK167869B1 (da) | Fremgangsmaade til fremstilling af zeolit af faujasittypen | |
| US3898319A (en) | Process for preparing zeolite Y | |
| JPS59156911A (ja) | 火山ガラスを主原料とするａ型ゼオライトの製造方法 | |
| GB2038301A (en) | Process for the production of zeolite A | |
| US2958579A (en) | Process for manufacture of molecular sieve adsorbents | |
| KR102271298B1 (ko) | 리튬 부산물을 이용한 제올라이트 제조 방법 | |
| NO801181L (no) | Krystallisering av zeolit a ved industrielle fremstillingsprosesser | |
| JP3262582B2 (ja) | ホージャサイト型ゼオライトの製造方法 | |
| JPH06263432A (ja) | シリカ質の廃吸着剤からの水ガラスの製造法および石英の分離精製法並びに該水ガラスからのメタケイ酸ナトリウム・九水塩またはゼオライトａの製造法。 | |
| SU998342A1 (ru) | Способ получени синтетического цеолита типа @ | |
| JPH0516372B2 (en]) | ||
| SU659525A1 (ru) | Способ получени метасиликата натри | |
| JPH0353251B2 (en]) |